QuickSwitch lets you switch network profiles on the fly (IP address, DNS, routes, NFS shares, etc.). There is a command-line configuration mode by which you can change your entire network setting in one line (including DNS and routing table). It is highly configurable, supports DHCP/BOOTP/NIS/NFS/etc., and also includes a curses-based GUI which you can use as a profile selector on startup.

Homepage: http://quickswitch.sourceforge.net/

freshmeat project page: http://freshmeat.net/projects/quickswitch/